Mössbauer spectroscopic study of some iron and antimony – containing minerals

نویسندگان

  • R Bayliss
  • F J Berry
  • M F Thomas
چکیده

Iron-57 Mössbauer spectra have been recorded from three minerals containing both iron and antimony. Schafarzikite of composition FeSb2O4 contains Fe. The Sb Mössbauer spectrum shows only the presence of Sb. The Fe Mössbauer spectrum corresponds with that recorded from a material of identical composition synthesised by a solid state reaction during the course of this work. Apuanite of formulation Fe20Sb16O48S4 contains both Fe and Fe in the ratio 1:3.35 The result is consistent with crystal structure determinations and the formulation of apuanite as Fe4Fe16Sb16O48S4. Versiliaite of composition Fe12Sb12O32S2 contains Feand Fe in the ratio 1:2.12 and, also consistent with structural characterisations, can be formulated Fe4Fe8Sb12O32S2.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Electronic structure of thallium filled skutterudites studied by x-ray absorption and Mössbauer spectroscopy

Thallium L III-edge x-ray absorption and iron-57 and tin-119 Mössbauer spectral measurements have been carried out to probe the electronic structure of the three sites in the filled skutterudite TlxCo42yFeySb12 and TlxCo4Sb122zSnz compounds with a range of x, y, and z values. The thallium L III-edge x-ray absorption spectra are independent of x, y, and z and are well reproduced by full multiple...

متن کامل

A Study of Iron in Fired Clay : Mössbauer Effect and Magnetic Measurements

A potters clay from the Gorgan plain, in N. E. Iran, has been fired successively at temperatures up to the melting point 1 200 "C in an atmosphere of air or 5 % CO in moist COz. Mossbauer spectra at 296 K and 4.2 K allow the determination of the relative amounts of iron in well-crystallised haematite or magnetite, of poorly-crystallised and fine-particle ferric oxide or hydroxide, and of iron d...

متن کامل

مطالعات کانی‌شناسی کانسار بوکسیت شهید نیلچیان (دوپلان)

Shahid Nilchian (Dopelan) deposit, located in high mountains of Chahar-Mahal Bakhtiari Province within the Zagros Thrust structural unit, is one of the main bauxite and argillite deposits of Iran. Many highly folded and faulted sedimentary successions are cropped in the area. The bauxite of Shahid Nilchian deposit is of lateritic type and belongs to Permo-Triassic in age. Five bauxite types wit...

متن کامل

The Potential for the Treatment of Antimony-Containing Wastewater by Iron-Based Adsorbents

Antimony (Sb) and its compounds are considered as global priority pollutants. Elevated concentrations of antimony in natural and industrial process wastewater are of global concern, particularly given interest in the potential toxicity and harm to the environment from aquatic exposure. Iron-based materials for treatment by adsorption are widely regarded to have potential merit for the removal o...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2009